文章信息/Info

Title:

Research Progress of Single Crystalline Organic Polymer Porous Materials

文章編號(hào):

1674-3962(2021)09-0712-10

作者:

朱嘉君; 軒婭慧; 蔣選豐

（湖北大學(xué)材料科學(xué)與工程學(xué)院，湖北 武漢，430062）

Author(s):

ZHU Jiajun;  XUAN Yahui;  JIANG Xuanfeng

（School of Materials Science and Engineering, Hubei University, Wuhan 430062, China）

關(guān)鍵詞:

共價(jià)聚合物; 單晶態(tài); 多孔材料; 模塊化組裝

Keywords:

organic polymer;  single crystalline;  porous material;  modular assembly

分類號(hào):

O631.1

DOI:

10.7502/j.issn.1674-3962.202104031

文獻(xiàn)標(biāo)志碼:

A

摘要:

單晶態(tài)有機(jī)聚合物多孔材料（single crystalline porous organic polymers）是一類非共價(jià)鍵與共價(jià)鍵協(xié)同驅(qū)動(dòng)的具有高結(jié)晶性和穩(wěn)定性的有機(jī)聚合物多孔材料。這類材料因具有比表面積大、密度低、結(jié)構(gòu)明確、孔徑可調(diào)等優(yōu)點(diǎn)，以及共價(jià)合成策略多樣和多領(lǐng)域應(yīng)用等優(yōu)勢(shì)而越來越受到人們的關(guān)注。總結(jié)了常見單晶態(tài)有機(jī)聚合物材料的幾種合成策略和原理，并按照合成方法的差異分3部分系統(tǒng)介紹了單晶態(tài)有機(jī)聚合物多孔材料的研究現(xiàn)狀，其中包括模塊化設(shè)計(jì)組裝方法和原理、多孔材料的結(jié)構(gòu)調(diào)控和晶體生長，以及這類材料在環(huán)境污染物的檢測和吸附、氣體的分離和存儲(chǔ)、光電器件、環(huán)境污染物傳感等方面的潛在應(yīng)用。基于此，對(duì)單晶態(tài)有機(jī)聚合物材料的精確合成和性能開發(fā)進(jìn)行了展望。

Abstract:

Single crystalline porous organic polymers are a kind of organic porous materials with high crystallinity and stability driven by non-covalent bonds and covalent bonds. Such well-defined material has the advantages of large specific surface area, low density, tunable structure, adjustable pores and modifiable reaction sites, etc. It has attracted much attention due to its diverse synthesis strategies and wide range of applications. In this review, the synthesis strategies and principles of common single crystalline porous organic polymer materials are summarized, and the recent progress of single crystalline porous organic polymer materials is also introduced briefly in three parts, including modular design concepts, structural control and crystal growth of porous organic polymer materials, and their potential applications in the detection and adsorption of environmental pollutants, gas separation and storage, photoelectronic and chemical sensing, etc. After that, the authors look forward to the precise synthesis and performance development of single crystalline organic polymer materials.