[1]董俊卿,李青會,干福熹,等.一批河南出土東周至宋代玻璃器的無損分析[J].中國材料進展,2012,(11):009-15.[doi:10.7502/j.issn.1674-3962.2012.11.02]
DONG Junqing,LI Qinghui,GAN Fuxi,et al.Non Destructive Analysis of Some Glass Artifacts Dated from Eastern Zhou to Song Dynasty Unearthed from Henan Province[J].MATERIALS CHINA,2012,(11):009-15.[doi:10.7502/j.issn.1674-3962.2012.11.02]
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一批河南出土東周至宋代玻璃器的無損分析(
)
中國材料進展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
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- 期數:
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2012年第11期
- 頁碼:
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009-15
- 欄目:
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特約研究論文
- 出版日期:
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2012-11-30
文章信息/Info
- Title:
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Non Destructive Analysis of Some Glass Artifacts Dated from Eastern Zhou to Song Dynasty Unearthed from Henan Province
- 作者:
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董俊卿; 李青會; 干福熹; 胡永慶; 程永建; 蔣宏杰
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（1中國科學院上海光學精密機械研究所科技考古中心，上海201800）
（2河南省文物考古研究所，河南 鄭州 450000）
（3洛陽文物考古研究院，河南 洛陽 471000）
（4南陽市文物考古研究所，河南 南陽 473000）
- Author(s):
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DONG Junqing; LI Qinghui; GAN Fuxi; HU Yongqing; CHENG Yongjian; JIANG Hongjie
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(1 Center of Scitech Archaeology, Shanghai Institute of Optics and Fine Mechanics,CAS, Shanghai 201800, China)
(2 Provincial Institute of Cultural Relics and Archeology of Henan, Zhengzhou 450000, China)
(3 Luoyang Municipal Institute of Cultural Relics, Luoyang 471000, China)
(4 Municipal Institute of Cultural Relics and Archeology of Nanyang, Nanyang 473000, China)
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- 關鍵詞:
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古代玻璃; 化學成分體系; 無損分析
- DOI:
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10.7502/j.issn.1674-3962.2012.11.02
- 摘要:
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為探索古代中原地區早期玻璃器的技術起源、發展和成分體系，選取了河南新鄭、南陽、滎陽和洛陽等地出土的一批東周至宋代的26件古代玻璃器及1件漢代釉陶器，利用外束PIXE和pXRF對其進行了無損分析。分析結果表明，不同時代玻璃器的化學成分體系存在一定差異。東周時期有Na2OCaOSiO2和PbOBaOSiO2兩種體系；漢代有PbOBaOSiO2、PbOSiO2和K2OCaOSiO2 3種體系；唐、宋時期則有Na2OCaOSiO2和PbOK2OSiO2兩種體系。結合以往研究成果，討論了器物來源、風化對定量分析的影響以及主要的著色離子等相關問題。其中，Na2OCaOSiO2體系玻璃為西方舶來品，其他系統的玻璃器為我國自制。由于表面風化，不同成分體系的古代玻璃都存在主要助熔劑的流失現象，流失程度與樣品風化程度密切相關。這些玻璃的不同著色特征，與過渡金屬元素密切相關。研究為探討早期中外玻璃貿易和技術交流，以及中國古代玻璃的起源與發展提供了新的科學依據。
- Abstract:
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To trace the technological origin, development and chemical composition system, in the present research, a total of 26 glass artifacts and 1 glazed pottery of the Han Dynasty were analyzed non destructively by means of external beam proton induced X ray emission (PIXE) and portable energy dispersive X ray fluorescence (p XRF) spectroscopy. These ancient glass artifacts dated from the Eastern Zhou to the Song Dynasty were unearthed from Xinzheng, Nanyang, Xingyang, Luoyang and other cities in Henan province. It is found that the chemical composition systems of these glass artifacts showed some different characteristics in different historic periods. During the Eastern Zhou, there were Na2OCaO SiO2 and PbO BaO SiO2 glasses. PbOBaOSiO2, PbOSiO2 and K2OCaOSiO2 glasses were found in the Han Dynasty. While in the Tang and Song Dynasties, both Na2OCaOSiO2 and PbOK2OSiO2 glasses were identified. Among them, the Na2OCaOSiO2 glasses were imported from the West and the others were native products of China. The main fluxes used in these ancient glasses were lost with different amount depending on the level of the surface weather. The versatile colors of these glasses were related to different transition metal elements. The results obtained provided some new clues to trace the early glasses trade and technical exchanges between China and abroad, and also to understand the origin and development of ancient Chinese glasses.
更新日期/Last Update:
2012-11-07