[1]胡紅巖,夏寅,靳治良,等.秦始皇帝陵及漢陽陵遺址成鹽元素及類型研究[J].中國材料進展,2012,(11):037-47.[doi:10.7502/j.issn.1674-3962.2012.11.06]
HU Hongyan,XIA Yin,JIN Zhiliang,et al.Study on the Salt Species and Types in the Emperor Qin s Mausoleum and Hanyangling Mausoleum Earthen Sites[J].MATERIALS CHINA,2012,(11):037-47.[doi:10.7502/j.issn.1674-3962.2012.11.06]
點擊復制
秦始皇帝陵及漢陽陵遺址成鹽元素及類型研究(
)
中國材料進展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
-
- 期數:
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2012年第11期
- 頁碼:
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037-47
- 欄目:
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特約研究論文
- 出版日期:
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2012-11-30
文章信息/Info
- Title:
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Study on the Salt Species and Types in the Emperor Qin s Mausoleum and Hanyangling Mausoleum Earthen Sites
- 作者:
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胡紅巖; 夏寅; 靳治良; 張尚欣; 容波; 王亮; 周鐵; 呂功煊; 李庫; 李崗
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（1 中國科學院蘭州化學物理研究所 羰基合成與選擇氧化國家重點實驗室，甘肅 蘭州 730000）
（2 秦始皇帝陵博物院 陶質彩繪文物保護國家文物局重點科研基地,陜西 西安 710600）
（3漢陽陵博物館,陜西 西安 712038 )
- Author(s):
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HU Hongyan1; XIA Yin2; JIN Zhiliang1; ZHANG Shangxin2; RONG Bo2; WANG Liang2; ZHOU Tie2; LU Gongxuan1; LI Ku3; LI Gang
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(1. State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,
Chinese Academy of Sciences, Lanzhou 730000, China)
(2.Emperor Qins Terracotta Warriors and Horses Museum, Xian 710600, China)
(3.Hanyangling Museum, Xian 712038, China)
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- 關鍵詞:
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土遺址; 鹽害; 成鹽元素; 成鹽類型
- DOI:
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10.7502/j.issn.1674-3962.2012.11.06
- 摘要:
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綜合運用X射線熒光光譜、X射線光電子能譜、X射線粉末衍射等技術對取自秦始皇帝陵、漢陽陵土遺址土樣中的成鹽元素、成鹽類型、鹽的晶體結構和類型進行了分析。結果表明，雖然各樣品之間存在著顯著差異，但樣品中多含有Na+、K+、NH+4、Mg2+、Ca2+、Cl-、SO2-4、NO-3、HCO-3等離子，可溶鹽或微溶鹽主要為NaCl、Na2SO4、NaNO3、NH4NO3、CaSO4·2H2O、2CaSO4·H2O、CaSO4、Na2Ca5(SO4)6·3H2O。結構分析表明，樣品中鹽的結晶形態取決于樣品的存賦地點和環境。這些結果對研究秦始皇帝陵和漢陽陵土遺址中鹽害的形成機理以及建立有效保護和防治體系具有重要指導意義。
- Abstract:
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The elements, salt type, and crystal structure of salts in the soil samples of the Terracotta Warriors and Horses of Qin Shihuang Mausoleum were analyzed by XRF、XPS、XRD in this paper, The results show that the soil samples contain Na+，K+，NH+4，Mg2+，Ca2+，Cl-，SO2-4，NO-3，HCO-3 ions. The soluble salts and slightly soluble salts in the samples are mainly NaCl、NaNO3、CaSO4·2H2O、2CaSO4·H2O、CaSO4、Na2Ca5(SO4)6·3H2O. The structures of salt samples were found to be dependent on the locations and environmental parameters of the Terracotta Warriors and Horses of Qin Shihuang Mausoleum. Those results are provided with the important guiding significance to study the formation mechanism of salt damages of the earthen heritage sites and to create system of availably protecting, preventing and cureing those heritages.
更新日期/Last Update:
2012-11-07