[1]黃燕,李鼎,孟竹,等.共價有機聚合物的合成及在燃料電池陰極氧還原反應中的應用[J].中國材料進展,2017,(7-8):041-45.[doi:10.7502/j.issn.1674-3962.2017.07.05]
HUANG Yan,LI Ding,MENG Zhu,et al.Synthesis and Application of Covalent Organic Polymers in Oxygen Reduction Reaction for Fuel Cell[J].MATERIALS CHINA,2017,(7-8):041-45.[doi:10.7502/j.issn.1674-3962.2017.07.05]
點擊復制
共價有機聚合物的合成及在燃料電池陰極氧還原反應中的應用(
)
中國材料進展[ISSN:1674-3962/CN:61-1473/TG]
- 卷:
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- 期數:
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2017年第7-8期
- 頁碼:
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041-45
- 欄目:
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前沿綜述
- 出版日期:
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2017-08-31
文章信息/Info
- Title:
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Synthesis and Application of Covalent Organic Polymers in Oxygen Reduction Reaction for Fuel Cell
- 作者:
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黃燕; 李鼎; 孟竹; 周卓航; 郭佳寧; 程元徽; 向中華
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北京化工大學分子能源材料研發中心，有機無機復合材料國家重點實驗室
- Author(s):
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HUANG Yan; LI Ding; MENG Zhu; ZHOU Zhuohang; GUO Jianing; CHENG Yuanhui; XIANG Zhonghua
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State Key Laboratory of OrganicInorganic Composites， Molecular Energy Materials R&D Center， Beijing University of Chemical Technology，
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- 關鍵詞:
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共價有機聚合物; 電催化; 氧還原反應; 燃料電池; 多孔聚合物
- Keywords:
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covalent organic polymers; electrocatalysts; oxygen reduction reaction; fuel cell; porous polymers
- DOI:
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10.7502/j.issn.1674-3962.2017.07.05
- 文獻標志碼:
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A
- 摘要:
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共價有機聚合物（Covalent Organic Polymers， COPs）是一類通過共價鍵將不同幾何構型和長度的有機配體組裝成多維度多功能的高水熱穩定性的有機多孔材料，具有高比表面積、孔道尺寸可控及結構多樣的特性，在能源的轉化和儲存領域應用前景廣闊。圍繞COP材料在燃料電池陰極氧還原催化領域中的應用，重點總結了二維、三維及功能化COP材料的合成策略與方法，及幾類代表性前驅體（卟啉類、三嗪類、聚苯胺類以及復合類）在氧還原電催化中的調控與性能研究。COP材料的定向裁剪和功能化，可為高效氧還原催化材料的制備提供便捷、豐富、可控的新型合成平臺，推動燃料電池新型催化劑的研發，為突破燃料電池工業應用提供新方案。
- Abstract:
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Covalent organic polymers (COPs) are a class of multidimensional， multifunctional and high hydrothermal stable organic porous materials， which are built via covalent bond of colorful organic building blocks. The high specific surface area， inherent optimized pore size and diverse structure contribute to its promising applications in the field of energy conversion and storage. In this review， we briefly summarize recent progress on efficient electrocatalysts for oxygen reduction reaction(ORR) basing on COPs in the fuel cell. First， we summarize the synthesis strategies of twodimensional， threedimensional and functional COPs， and subsequently review the ORR performance of COP materials according to four types of representative precursors， i.e.， porphyrins， triazines， polyanilines and hybrids. Due to tunable structural characteristics and multichemical functionality， COP materials can offer convenient， abundant and controllable new synthetic platform for preparation of efficient ORR electrocatalysts， promote research of new fuel cell catalyst， and provide new solutions for breakthrough of fuel cell for industrial applications.
更新日期/Last Update:
2017-09-07