文章信息/Info

Title:

Application and Challenges of Solar Cells Using Metal Organic Framework Materials

文章編號:

1674-3962(2021)08-0618-08

作者:

歐金花1; 胡波年1; 何賽玉1; 王薇1; 劉進軒2

(1.湖南工學院材料與化學工程學院，湖南 衡陽 421002) (2.大連理工大學 精細化工國家重點實驗室，遼寧 大連 116024)

Author(s):

OU Jinhua1;  HU Bonian1;  HE Saiyu1;  WANG Wei1;  LIU Jinxuan2

(1. Department of Material and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China) (2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, China)

關鍵詞:

太陽能電池; 金屬�灿袡C框架材料; 光伏技術; 效率; 穩定性

Keywords:

solar cells;  metal organic framework materials;  photovoltaic technology;  efficiency;  stability

分類號:

TM914.4

DOI:

10.7502/j.issn.1674-3962.202004024

文獻標志碼:

A

摘要:

化石能源枯竭、溫室效應以及環境惡化是人類生存發展面臨的巨大挑戰，發展可再生能源對當代社會至關重要。第三代太陽能電池包括染料敏化太陽能電池、鈣鈦礦太陽能電池、有機聚合物太陽能電池等具有轉化效率高、加工成本低、環境友好等特點，吸引了科研工作者的廣泛關注。提高太陽能器件的效率和穩定性，對推動其工業化進程具有重要意義。金屬-有機框架材料（metal organic framework materials，MOFs）是由金屬團簇和有機單體有序排列形成的一類新型化合物，在氣體儲存和分離領域得到了廣泛研究。近年來，MOFs因其高結晶性、高比表面積和多孔性等特點成為光伏技術領域的研究熱點，用以提高器件的光電轉化效率和長期穩定性。主要總結了近年來MOFs及衍生材料在染料敏化太陽能電池、鈣鈦礦太陽能電池、有機聚合物太陽能電池中的應用和突破性進展，并展望MOFs在光伏技術領域的應用前景。

Abstract:

The development of renewable energy is vital to modern life due to the challenges from the depletion of fossil energy, the greenhouse effect and the deterioration of the environment. The third generation of solar cells including dye-sensitized solar cells, perovskite solar cells and organic polymer solar cells, are characterized by high conversion efficiency, low processing cost and environmental friendliness, they have attracted tremendous scientific and industrial attention in the past two decades. It is greatly significative to improve the efficiency and stability of solar energy devices for promoting their industrialization. Metal organic framework materials (MOFs) is a new kind of compound arranged with metal clusters and organic monomers, which is widely studied in the field of gas storage and separation. In recent years, MOFs is also used in photovoltaic technology to improve the incident photon-to-electron conversion efficiency and stability of device due to its high crystallinity, huge specific surface area and porosity. The review focuses on the summary of the applications and breakthroughs of MOFs and their derivatives in dye-sensitized solar cells, perovskite solar cells and organic polymer solar cells in recent years, aiming to provide references for the prospect of photovoltaic technology in the future.