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[1]劉艷明,賈新碌,張依偲,等.鈦及鈦鋁合金的高溫氧化行為與防護[J].中國材料進展,2023,42(09):699-721.[doi:10.7502/j.issn.1674-3962.202204007]
 LIU Yanming,JIA Xinlu,ZHANG Yicai,et al.High Temperature Oxidation Behaviors and Protection of Ti-Based and TiAl-Based Alloys[J].MATERIALS CHINA,2023,42(09):699-721.[doi:10.7502/j.issn.1674-3962.202204007]
點擊復制

鈦及鈦鋁合金的高溫氧化行為與防護()
分享到:

中國材料進展[ISSN:1674-3962/CN:61-1473/TG]

卷:
42
期數:
2023年第09期
頁碼:
699-721
欄目:
出版日期:
2023-09-30

文章信息/Info

Title:
High Temperature Oxidation Behaviors and Protection of Ti-Based and TiAl-Based Alloys
文章編號:
1674-3962(2023)09-0699-23
作者:
劉艷明12賈新碌12張依偲12趙興興12汪欣3
1. 西安石油大學材料科學與工程學院,陜西 西安 710065 2. 西安市高性能油氣田材料重點實驗室,陜西 西安 710065 3. 西北有色金屬研究院,陜西 西安 710016
Author(s):
LIU Yanming12 JIA Xinlu12 ZHANG Yicai12 ZHAO Xingxing12 WANG Xin3
1. College of Materials Science and Engineering, Xi’an Shiyou University, Xi’an 710065, China 2. Xi’an Key Laboratory of High Performance Oil and Gas Field Materials, Xi’an 710065, China 3. Northwest Institute for Non-Ferrous Metal Research, Xi’an 710016, China
關鍵詞:
鈦合金高溫氧化合金化高溫防護涂層失效機理
Keywords:
titanium alloys high temperature oxidation alloying high temperature protection coatings failure mechanisms
分類號:
TG146.23; TG178
DOI:
10.7502/j.issn.1674-3962.202204007
文獻標志碼:
A
摘要:
鈦及鈦鋁合金在航空航天領域應用廣泛,但抗高溫氧化性能不足是制約其發展的主要原因之一。基于幾種典型鈦合金(工業純鈦、近α-Ti合金、α+β鈦合金、β鈦合金)和鈦鋁合金(γ-TiAl、Ti3Al)的高溫氧化行為、氧化特點及失效機制,回顧了改善鈦及鈦鋁合金抗高溫氧化性能的主要途徑,即合金化及表面改性。合金化需優化合金成分及含量,對鈦及鈦鋁合金的抗高溫氧化性能改善有限。表面改性包括涂覆高溫防護涂層、表面合金化及表面強化,介紹了鈦及鈦鋁合金表面9種防護涂層的發展現狀,即Al涂層、Al-X涂層、Ti-Al-X涂層、MCrAlY涂層、準晶涂層、高熵合金涂層、惰性氧化物陶瓷涂層、搪瓷涂層及氮化物陶瓷涂層,總結了這些涂層的制備方法、高溫防護機理、改性手段、失效機制及應用局限。此外,介紹了4種表面合金化技術(熱擴散、離子注入、預氧化及激光表面合金化)及表面強化技術在鈦及鈦鋁合金高溫防護中的應用現狀。現階段,結合計算機模擬、機器學習等先進手段,設計制備新型高溫鈦合金結構材料,同時設計和發展具有優異綜合性能的高溫防護涂層及相應的高效制備方法,是促進鈦及鈦鋁合金高溫應用的發展方向。
Abstract:
Titanium and titanium aluminides alloys have been widely used in the aerospace industry, but the lack of high temperature oxidation resistance is one of the main reasons that restrict their development. Based on the high temperature oxidation behavior, oxidation characteristics and failure mechanisms of several typical Ti-based alloys (industrial pure titanium, near αTi, α+β-Ti, β-Ti) and TiAl-based alloys (γ-TiAl, Ti3Al), the main ways (i.e,alloying and surface modification) to improve their high temperature oxidation resistance are reviewed. Optimizing the composition and content of the alloy element is necessary for alloying, which has limited effect on improving the high temperature oxidation resistance of Ti-based alloys and TiAl-based alloys. Surface modification includes applying high temperature protective coating, surface alloying and surface strengthening. Here, the development status of the nine typical high temperature protective coating systems for the Ti-based and TiAl-based alloys is reviewed,including Al coatings, Al-X coatings, Ti-Al-X coatings, MCrAlY coatings, quasicrystalline coatings, high-entropy alloy coatings, inert oxide ceramic coatings, enamel coating and nitride ceramic coatings. Furthermore, their processing methods, high temperature protection mechanisms, modification methods, failure mechanisms and application limitations are summarized. In addition, the application status of surface alloying technologies namely thermal diffusion, ion implantation, pre-oxidation and laser surface alloying as well as the surface strengthening technology in the high temperature protection of Ti-based and TiAl-based alloys are introduced. At this stage, advanced methods such as computer simulation and machine learning can be combined to design and prepare new high-temperature Ti-based structural materials. At the same time, developing the high-temperature protective coatings with excellent comprehensive properties and the corresponding efficient preparation methods is the key to promote the high-temperature application of Ti-based and TiAl-based alloys.

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備注/Memo

備注/Memo:
收稿日期:2022-04-06修回日期:2022-11-27 基金項目:國家自然科學基金項目(51701157,52071274);陜西省自然科學基礎研究計劃項目(2022JM-261);陜西省創新人才推動計劃青年科技新星項目(2020KJXX-062);西安石油大學研究生創新項目(YCS21111018);陜西省 大學生創新創業訓練項目(S202110705065) 第一作者:劉艷明,女,1988年生,副教授,碩士生導師 通訊作者:汪欣,男,1987年生,教授級高級工程師, 碩士生導師,Email:wangx@alum.imr.ac.cn
更新日期/Last Update: 2023-08-28
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