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[1]張寶,梁禎,張雁南,等.廢舊鋰離子電池正極材料回收研究進展[J].中國材料進展,2024,43(05):380-391.[doi:10.7502/j.issn.1674-3962.202308031]
　ZHANG Bao,LIANG Zhen,ZHANG Yannan,et al.Research Progress on Cathode Material Recycling of Waste Lithium-Ion Batteries[J].MATERIALS CHINA,2024,43(05):380-391.[doi:10.7502/j.issn.1674-3962.202308031]
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廢舊鋰離子電池正極材料回收研究進展()
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中國材料進展[ISSN:1674-3962/CN:61-1473/TG]

卷:
43
期數:
2024年第05期
頁碼:
380-391
欄目:
出版日期:
2024-05-30

文章信息/Info

Title:
Research Progress on Cathode Material Recycling of Waste Lithium-Ion Batteries
文章編號:
1674-3962(2024)05-0380-12
作者:
張寶; 梁禎; 張雁南; 孟奇; 董鵬; 張英杰
1.昆明理工大學冶金與能源工程學院 鋰離子電池及材料制備技術國家地方聯合工程研究中心，云南 昆明 650093 2．昆明理工大學材料科學與工程學院，云南 昆明 650093
Author(s):
ZHANG Bao;  LIANG Zhen;  ZHANG Yannan;  MENG Qi;  DONG Peng;  ZHANG Yingjie
1. School of Metallurgy and Energy Engineering, Kunming University of Science and Technology, State Joint Engineering Research Center for Lithium-ion Battery and Material Preparation Technology, Kunming 650093, Yunnan, China. 2. School of Materials Science and Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China
關鍵詞:
廢舊鋰離子電池; 正極材料; 預處理工藝; 回收工藝; 直接回收
Keywords:
waste lithium-ion batteries;  cathode materials;  pretreatment process;  recycling process;  direct recovery
分類號:
TF803；TQ09
DOI:
10.7502/j.issn.1674-3962.202308031
文獻標志碼:
A
摘要:
隨著鋰離子電池（lithium-ion batteries，LIBs）在電動汽車、3C電子產品和儲能領域的大規模應用和產銷量的日益劇增，其退役后帶來的金屬浪費和環境污染問題也日益突出。有必要大力開發綠色環保、高效低成本的廢舊鋰離子電池正極材料回收工藝，實現金屬資源的周期性利用。回顧了廢舊鋰離子電池正極材料回收工藝的最新進展。概述了現有的回收工藝，詳細介紹了預處理、火法冶金、濕法冶金、生物浸出和直接回收等回收工藝的研究現狀。并通過對比分析現有技術存在的問題，綜合討論了各工藝的回收效率、安全性和經濟價值。最后，展望了廢舊鋰離子電池正極材料回收再利用的前景和發展趨勢，旨在為直接化、高值化、規模化的廢舊鋰電池回收再利用研究提供借鑒與參考。
Abstract:
With the increasing large-scale application and production as well as the sales of lithium-ion batteries (LIBs) in electric vehicles, 3C electronics and energy storage devices, the metal waste and environmental pollution caused by their retirement are also becoming increasingly prominent. It is necessary to vigorously develop a green, environmentally friendly, efficient and low-cost cathode material recycling process for waste lithium-ion batteries to realize the cycle utilization of non-ferrous metal resources. This paper reviews the latest progress in the material recycling process of cathode materials for the used lithium-ion batteries. The existing recovery processes are summarized.Moreover, the research status of recovery processes such as the pretreatment, pyrometallurgy, hydrometallurgy, biological leaching and direct recovery strategy are detailed illustrated. The problems and the advantages of these technology are compared and analyzed. Furthermore, the recovery efficiency, safety and economic value are comprehensively discussed. Finally, the prospect and development trend of the recycling and reuse of cathode materials of used lithium-ion batteries are outlooked, aiming at the direct, high-value and large-scale research on the recycling and reuse of used lithium batteries to provide lessons and references.

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